杨占会

时间:2018-02-23浏览:9638

杨占会,男,博士,教授,硕士生导师,中共党员

电子邮箱:zhyang@buct.edu.cn

办公室地址及电话: 科技楼1105


教育经历

2010-2015年:北京化工大学有机化学系,获博士学位;

2006-2010年:北京化工大学应用化学系,获学士学位。


工作经历

2024.01-至今:北京化工大学,化学学院,教授;

2018.01-2024.01:北京化工大学,理学院、化学学院,副教授;

2017.11-2018.01:北京化工大学,理学院,讲师;

2016.08-2017.08:美国威斯康辛大学麦迪逊分校,药学院,访问学者;

2015.07-2017.10:北京化工大学,化学工程与技术,博士后。

主讲课程

本科生《有机化学》(112学时)、研究生《高等有机化学II》(48学时)、《高等有机合成化学》(48学时)


主持或参与的科研项目

1、主持:2024-2027 国家自然科学基金面上项目:基于生成α-硫羰基卡宾的新途径构筑手性硫杂环,在研;

2、参与:2022-2025 国家重点研发计划重点专项子课题《高纯手性稀土有机配合物试剂合成技术开发及应用》,在研;

3、主持:2020-2022北京市自然科学面上项目:基于新型铱催化剂的水相不对称转移氢化,已结题;

4、主持:2017-2019国家自然科学青年基金:基于硫羰基卡宾的五元和七元硫杂环合成,已结题;

5、主持:2015-2016中国博士后科学基金项目:硫代-Staudinger环加成的关环机理研究,已结题;

6、主持多项企业技术开发项目。


主要研究领域或方向

药物合成导向的绿色有机合成与催化:基于α-硫羰基卡宾的催化成环反应、基于金属氢化物的绿色催化转移氢化。


科研论文

迄今发表SCI论文70余篇,其中第一/通讯作者共发表SCI论文近70篇。

https://www.researchgate.net/profile/Zhanhui-Yang

https://orcid.org/0000-0001-7050-8780


部分代表性论文如下:

1.  Yang Chen, Jingyu Zhang, Hongguang Du,* Renshi Luo,* Jiaxi Xu, Zhanhui Yang*. Iridium-catalyzed reductive γ-lactonization of ortho-acylbenzoic acids in water: sustainable access to phthalides. Org. Chem. Front., 2024, https://doi.org/10.1039/D3QO02019C.

2.  Tingting Wang, Rui Miao, Renshi Luo, Jiaxi Xu, Zhanhui Yang*. Furan-2-yl Anions as γ-Oxo/Hydroxyl Acyl Anion Equivalents Enabled by Iridium-Catalyzed Chemoselective Reduction. Org. Lett. 2023, 25, 4705-4710.

3.  Lu Ouyang, Rui Miao, Zhanhui Yang*, Renshi Luo*. Iridium-catalyzed reductive amination of carboxylic acids. J. Catal. 2023, 418, 283-289.

4.  Lu Ouyang, Yuqiu Liang, Sen Wang, Rui Miao, Jianhua Liao, Zhanhui Yang*, Renshi Luo*. Iridium-catalyzed reductive hydroamination of terminal alkynes in water. J. Catal. 2023, 427, 115096.

5.  Cunzhi Chen, Shuyan Fang, Mingwu Yu, Jiaxi Xu and Zhanhui Yang*. Catalytic site-specific and regioselective (3 + 2) transannulations between 1,2,3-thiadiazoles and allenoates. Org. Chem. Front. 2023, 10, 661-667. https://doi.org/10.1039/D2QO01662A.

6.  Cunzhi Chen, Shuyan Fang, Ziyang Dong, Jiaxi Xu, and Zhanhui Yang*Catalytic Diastereospecific and Enantioselective (3+2) Transannulations of 1,2,3-Thiadiazoles with Strained Norbornene Derivatives. Org. Lett. 2022, 24, 2110–2114. DOI: 10.1021/acs.orglett.2c00330.

7.  Ziyang Dong, Meng-Yao Ma, Jiaxi Xu and Zhanhui Yang*. Catalytic (3 + 2) umpolung annulations of α-thioacyl carbenes with aryl isothiocyanates. Chem. Commun. 2022, 58, 7980-7983. DOI: 10.1039/D2CC02882D.

8.  Changmeng Liu, Yang Chen, and Zhanhui Yang*. Iridium-Catalyzed Stereoselective Transfer Hydrogenation of 1,5-Benzodiazepines. J. Org. Chem.  2022, 87, 12001-12018. DOI: 10.1021/acs.joc.2c01006.

9.  Zhanhui Yang*. Partial reductions of carboxylic acids and their derivatives to aldehydes. Org. Chem. Front. 2022, 9, 3908-3931. DOI: 10.1039/D2QO00748G.

10.  Ziyang Dong, Cunzhi Chen, Jing Wang, Jiaxi Xu and Zhanhui Yang*. Two dual roles of bisphosphine and epoxy: Rh-catalyzed highly chemo- and diastereoselective (3 + 2) transannulations of 1,2,3-thiadiazoles with cyanoepoxides. Org. Chem. Front.2021, 8, 6687–6698. https://doi.org/10.1039/D1QO01220G.

11.  Dong Xu, Yang Chen, Changmeng Liu, Jiaxi Xu and Zhanhui Yang*. Iridium-catalyzed highly chemoselective and efficient reduction of nitroalkenes to nitroalkanes in water. Green Chem. 2021, 23, 6050-6058. https://doi.org/10.1039/D1GC01907D.

12.  Yang Chen, Siqi Li, Shili Hou, Jiaxi Xu*, and Zhanhui Yang*. Chiral Synthesis of McGeachin-Type Bisaminals. J. Org. Chem.2020, 85, 3709-3716. https://pubs.acs.org/doi/10.1021/acs.joc.9b03362.

13.  Jide Li, Weiping Tang, Demin Ren, Jiaxi Xu * and Zhanhui Yang*. Iridium-catalysed highly selective reduction–elimination of steroidal 4-en-3-ones to 3,5-dienes in water. Green Chem. 2019, 21, 2088-2094. https://doi.org/10.1039/C9GC00654K.

14.  Bingnan Zhou, Qiuyue Wu, Ziyang Dong, Jiaxi Xu*, and Zhanhui Yang*. Rhodium-Catalyzed 1,1-Hydroacylation of Thioacyl Carbenes with Alkynyl Aldehydes and Subsequent Cyclization. Org. Lett.2019, 21, 3594-3599. https://pubs.acs.org/doi/10.1021/acs.orglett.9b01003.

15.  Yang Chen, Hongyi Qi, Ning Chen, Demin Ren, Jiaxi Xu*, and Zhanhui Yang*. Fluorium-Initiated Dealkylative Cyanation of Thioethers to Thiocyanates. J. Org. Chem.2019, 84, 9044-9050. https://pubs.acs.org/doi/10.1021/acs.joc.9b00965.

16.  Shiyi Yang, Weiping Tang, Zhanhui Yang* and Jiaxi Xu*. Iridium-catalyzed highly efficient and site-selective deoxygenation of alcohols in water. ACS Catal.2018, 8, 9320–9326. https://pubs.acs.org/doi/10.1021/acscatal.8b02495.

17.  Zhicheng Fu, Wenhao Yuan, Ning Chen, Zhanhui Yang* and Jiaxi Xu*. Na2S2O8-mediated efficient synthesis of isothiocyanates from primary amines in water. Green Chem.2018, 20, 4484–4491. https://doi.org/10.1039/C8GC02261E.

18.  Ji-tian Liu, Shiyi Yang, Weiping Tang, Zhanhui Yang* and Jiaxi Xu*. Iridium-catalyzed efficient reduction of ketones in water with formic acid as a hydride donor at low catalyst loading. Green Chem.2018, 20, 2118-2124. https://doi.org/10.1039/C8GC00348C.


教改论文

1. 杨占会*, 陈宁. 卤代烷亲卤取代反应的理论基础与影响因素. 化学教育(中英文), 2023, 44(6): 181-184.

2. 杨占会*, 许家喜. 烯烃的羟汞化脱汞:还原脱汞机理. 化学教育(中英文), 2023, 44(2): 117-122.

3. 杨占会*, 陈洋. 端炔的硼化-迁移加成-氧化和硼化-氧化. 大学化学, 2021, 36(4): 2005028.

4. 董子阳, 杨占会*, 许家喜. 关于规范两种马钱子生物碱中文译名的建议. 大学化学, 2021, 36 (4): 2005056.

5. 杨占会*, 沈旭凡. 苯的凯库勒式与苯的共振结构. 大学化学, 2021, 36(8): 2009012.

6. 杨占会*, 沈旭凡. 杜瓦苯与苯的共振结构. 大学化学, 2021, 36(6): 2008014.

7. 杨占会*, 许家喜*. 有机化学课程中的绿色发展理念. 大学化学, 2020, 35(7): 99-103.

8. 杨占会*, 许家喜. 关于区分有机分子对称性中文表述的建议. 大学化学, 2020, 35(7): 181-184.

9. 杨占会*. 对“红铝”译名的异见. 大学化学, 2020, 35(7): 185-186.


招生专业:

有机化学及相关专业。


招生要求:

态度端正,热爱有机;踏实能干,勇于挑战。