Jingbin Han
Professor
Beijing University of Chemical Technology
Email:hanjb@mail.buct.edu.cn
Office: 225 Wuji Building
Lab: 312 Advanced Innovation Center
Research Interests
We focus on the structural design, assembly, and performance regulation of intercalated functional materials. The current study addresses three categories of intercalated functional materials that exhibit distinct structural features, utilizing layered double hydroxides (LDHs) as the principal material. 1. Gas barrier thin film materials: the adjustable main-guest structure and interlayer microenvironment of LDHs are utilized to produce inorganic/organic functional materials with strong gas barrier properties. These materials are assembled with polymer matrices to create gas barrier thin films that find applications in tire air-tight layers, high-moisture-retaining agricultural films, and LED sealing adhesives. 2. Two-dimensional separation membrane materials: guided by the specific substances to be separated, LDHs are designed and assembled into two-dimensional separation layered membranes that possess adjustable interlayer channel size, hydrophilicity, and positively charged characteristics. These membranes demonstrate excellent separation performance in a variety of molecular and ion separation fields. 3. LDH inorganic supramolecular solid fillers: the functional properties of LDHs, including antioxidative and lubricative capabilities, are leveraged to produce LDH inorganic supramolecular solid fillers. These fillers are employed in lubricating oils and fats and are practically applied in large gears, automobiles, and other fields.
We are also interested in exploring approaches to secondary anion batteries design for reversible green energy storage and conversion. For conventional secondary cation batteries, scarce and expensive Li is often used, leading to high prices and formation of metal dendrites. The utilization of Na or Mg with large ionic radius still cannot avoid safety issues and large volume expansion of electrode materials. New anionic battery-based energy systems possess the advantages of high safety and low expansion of electrode materials as well as high abundance of raw materials, reducing the manufacturing costs. We have innovatively developed the rechargeable anion batteries based on layered double hydroxides (LDHs), including chlorine-ion batteries (CIBs), fluorine-ion batteries (FIBs) and bromine-ion batteries (BIBs). We are interested in the construction and study of optimized LDHs and improved configuration of battery components with the potential to access excellent electrochemical performances such as high discharge capacity and voltage platform during the battery design. Aqueous anion batteries, featuring a brine solution electrolyte with clean, renewable, and safe characteristics, will be our future research hotspot for novel design of green energy storage.
Awards &hornours
1. Young Scholar of the "National High-Level Talent Planning", 2023.
2. Hou Debang Youth Award in Chemical Science and Technology, 2018.
3. "Beijing City Rising Stars" Program, 2016.
4. "Youth Talent Support Program" by the China Association for Science and Technology, 2016.
5. First Prize of Scientific and Technological Progress Award by the Petrochemical Association, 2015 (as a participant).
6. Nominee for the "National Excellent Doctoral Dissertation" Award, 2013.
7. "Beijing Excellent Doctoral Dissertation" Award, 2012.
Projects &Funding
1. National 863 Project: Development and Demonstration of Key Technologies for Clean Production of Layered Structural Advanced Composite Materials. (Principal Investigator)
2. National Natural Science Foundation of China (NSFC) General Project: Construction and Performance Study of LDHs-based Gas Barrier Thin Films. (Principal Investigator)
3. NSFC Youth Project: Synthesis and Supercapacitive Performance of LDHs with Interlayer Structure. (Principal Investigator)
4. International Collaborative Project: Large-scale Preparation Technology of High Surface Area LDHs. (Participant)
5. National 973 Project: Functional Assembly and Efficient Utilization of Nano-intercalated Materials and Salt Lake Magnesium Resources. (Participant)
6. NSFC Key Project: Assembly and Optical Properties of Supramolecular Intercalated Structure Crystalline Functional Thin Film Materials. (Participant)
Publications (selected)
[1] Biao Li, Zeya Yang, Yibo Dou, Jian Zhang, Jun Lu*, and Jingbin Han*, Two-dimensional LDH films templating for controlled preparation and performance enhancement of polyamide nanofiltration membranes, Angew. Chem. Int. Ed., 2023, e202304442.
[2] Jian Zhang, Tianyong Liu, Qingyan Yuan, Biao Li, Yunjia Wu, Yibo Dou, Xin Zhang andJingbin Han*, Low volume-expansion, insertion-type layered silicate hierarchical structure for superior storage of Li, Na, K, Adv. Funct. Mater., 2023, 2301914.
[3] Xiaozhi Xu, Jinhui Han, Biao Li, Zeya Yang, Yibo Dou, and Jingbin Han*, Precise control on two-dimensional nanochannels at sub-nanometer level for customizable gas separation, AIChE J., 2023, e18167.
[4] Biao Li, Juanjuan Peng, Menghan Li, Zeya Yang, Jun Lu and Jingbin Han*, Facile synthesis and exfoliation of micro-sized LDH to fabricate 2D membranes towards Mg/Li separation, AIChE J., 2023, e18212
[5] Qing Yin, Tongde Wang, Zhihao Song, Shuhan Yang, Yidong Miao, Yunjia Wu, Yanwei Sui,* Jiqiu Qi, Yongzhi Li, Danyang Zhao, Guohua Gao,* Jingbin Han*, Computational high-throughput screening of layered double hydroxides as cathodes for chloride ion batteries, Chem. Eng. J., 2023, 459, 141545.
[6] Zelin Wu, Yunjia Wu, Qingyan Yuan, Jian Zhang, Yibo Dou, and Jingbin Han*, Aqueous chloride ion battery within neutral electrolyte based on CoFe-Cl layered double hydroxide anode, ACS Appl. Mater. Interface, 2023, 15, 38540.
[7] Zhihao Song, Qing Yin*, Shuhan Yang, Yidong Miao, Yunjia Wu, Yong-Zhi Li, Yaojian Ren, Yanwei Sui, Jiqiu Qi and Jingbin Han*, A high-nickel layered double hydroxides cathodes boosting the rate capability for chloride ion batteries with ultralong cycling life, Small, 2023, 19, 2302896.
[8] Fusong Chen, Xiaotong Ma, Xin Cao, Yibo Dou*, Shanyue Guan, Xiaochen Qiu* and Jingbin Han*, An effective antioxidant to mitigate reperfusion injury by tailoring CeO2 electronic structure on layered double hydroxide nanosheets, Chem. Eng. J., 2023, 475, 146190.
[9] Zeya Yang, Biao Li, Shuangde Li, Yibo Dou*, and Jingbin Han*, Layered double hydroxide/PBAT hybrid films with simultaneously high-barrier and degradable properties, Chem. Eng. Sci. 2023, 119016.
[10] Xiaozhi Xu, Lingyu Zhang, Biao Li, Zeya Yang, Jingbin Han*, Modulation on interlayer channels of LDH/polymer hybrid membranes for efficient CO2 separation, Appl. Surf. Sci., 2023, 618, 156651.
[11] Biao Li, Xiaozhi Xu, Zeya, Yang, Jun Lu, Jingbin Han*, Recent advances in layered-double-hydroxide-based separation membranes, ChemPlusChem, 2023, e202300521.
[12] Yong Li, Qiang Zhang, Weidong Zhou, Yongwang Huang and Jingbin Han*, Study on the dispersion and lubrication properties of LDH in lubricating oil, Lubricants, 2023, 11, 147.
[13] Zeya Yang, Kaiqiang Shi, Zuchao Jin, Ziru Liu, Yong Li*, Yongwang Huang, Feng Gao, and Jingbin Han*, Biodegradable layered double hydroxide/polymer films for efficient oxygen and water vapor barriers, Ind. Eng. Chem. Res., 2022, 61, 1367.
[14] Jian Zhang, Tianlin Li, Qingyan Yuan, Yunjia Wu, Yibo Dou, and Jingbin Han*, MgAl saponite as a transition-metal-free anode material for lithium-Ion batteries, ACS Appl. Mater. Interface, 2022, 14, 54812.
[15] Shuoxiao Zhang, Tongde Wang, Jian Zhang, Yidong Miao, Qing Yin, Zelin Wu, Yunjia Wu, Qingyan Yuan, and Jingbin Han*, A zero-strain insertion cathode material for room-temperature fluoride-ion batteries, ACS Appl. Mater. Interface, 2022, 14, 24518.
[16] Jian Zhang, Qing Yin, Yunjia Wu, Shuoxiao Zhang, Kai-Jie Wang*, Jingbin Han*, Fe saponite, a layered silicate for reversible lithium-ions storage with large diffusion coefficient, J. Energy Chem., 2022, 67, 92.
[17] Xiaozhi Xu, Jiajie Wang, Awu Zhou, Siyuan Dong, Kaiqiang Shi, Biao Li, Jingbin Han*, and Dermot O’Hare*, High-efficiency CO2 separation using hybrid LDH polymer membranes, Nat. Commun., 2021, 12, 3069.
[18] Kaiqiang Shi, Xiaozhi Xu, Siyuan Dong, Biao Li, Jingbin Han*, Stretchable gas barrier films achieved by hydrogen-bond self-assembly of nano-brick multilayers, AIChE J., 2021, 67, e17373.
[19] Qing Yin, Jianeng Luo, Jian Zhang, Shuoxiao Zhang, Jingbin Han*, Yanjun Lin, Jisheng Zhou, Lirong Zheng, and Min Wei, Ultralong-life chloride ion batteries achieved by the synergistic contribution of intralayer metals in layered double hydroxides. Adv. Funct. Mater., 2020, 30, 1907448.
[20] Qing Yin, Jian Zhang, Jianeng Luo, Mingfei Shao, Min Wei, Jingbin Han*, A new family of rechargeable batteries based on halide ions shuttling. Chem. Eng. J., 2020, 389, 124376.
[21] Qin Yin#, Jianeng Luo#, Jian Zhang, Guoqing Cui, Lirong Zheng, Jingbin Han* and Dermot O’Hare*, High-performance, long lifetime chloride ion battery using a NiFe-Cl layered double hydroxide cathode. J. Mater. Chem. A., 2020, 8, 12548.
[22] Qing Yin, Deming Rao, Guanjun Zhang, Yajun Zhao, Jingbin Han,* Kun Lin, Lirong Zheng, Jian Zhang, Jisheng Zhou,* Min Wei, CoFe-Cl layered double hydroxide: a new cathode material for high-performance chloride ion batteries, Adv. Funct. Mater., 2019, 1900983.
[22] Yajun Zhao, Tao Sun, Qing Yin, Jian Zhang, Shuoxiao Zhang, Jianeng Luo, Hong Yan, Lirong Zheng, Jingbin Han* and Min Wei, Discovery of a new intercalation-type anode for high-performance sodium ion batteries, J. Mater. Chem. A, 2019, 7, 15371.
[23] Siyuan Dong, Yingqi Jia, Xiaozhi Xu, Jianeng Luo, Jingbin Han*, and Xiaoli Sun, Crystallization and properties of poly(ethylene terephthalate)/layered double hydroxide nanocomposites, J. Colloid Interface Sci., 2019, 539, 54.
[24] Jiajie Wang, Xiaozhi Xu, Jian Zhang, Mengting Chen, Siyuan Dong, Jingbin Han*, Min Wei, Moisture-permeable, humidity-enhanced gas barrier films based on organic/inorganic multilayers, ACS Appl. Mater. Interface, 2018, 10, 28130.
[25] Xiaozhi Xu, Lumei Wang, Jiajie Wang, Qing Yin, Jingbin Han*, Min Wei, Hydroxide-ion-conductive, gas barrier films based on layered double hydroxide/polysulfone multilayers, Chem. Commun., 2018, 54, 7778.
[26] Chong Wang, Bin Ma, Simin Xu, Dapeng Li, Shan He, Yufei Zhao, Jingbin Han*, Min Wei*, David G. Evans, Xue Duan, Visible-light-driven overall water splitting with a largely-enhanced efficiency over a Cu2O@ZnCr-layered double hydroxide photocatalyst, Nano Energy, 2017, 32, 463.
[27] Yibo Dou, Shitong Zhang, Ting Pan, Simin Xu, Awu Zhou, Min Pu, Hong Yan, Jingbin Han*, Min Wei*, David G. Evans, Xue Duan, TiO2@layered double hydroxide core-shell nanospheres with largely enhanced photocatalytic activity toward O2 generation, Adv. Funct. Mater., 2015, 25, 2243.
[28] Yibo Dou, Ting Pan, Simin Xu, Hong Yan, Jingbin Han*, Min Wei*, David G. Evans, Xue Duan, Transparent, ultrahigh-gas-barrier films with a brick-mortar-sand structure, Angew. Chem. Int. Ed., 2015, 54, 9673.
[29] Jingbin Han, Yibo Dou, Jingwen Zhao, Min Wei*, David G. Evans, Xue Duan， Flexible Co-Al LDH@PEDOT core/shell nanoplatelet array for high-performance energy storage, Small, 2013, 9, 98.
[30] Jingbin Han, Yibo Dou, Min Wei, David G. Evans, Xue Duan, Erasable nanoporous antireflection coatings based on the reconstruction effect of layered double hydroxides, Angew. Chem. Int. Ed., 2010, 49, 2171.